Yes. When selecting a USPS service on the READY TO SHIP page, you are able to add a USPS pickup request by simply selecting the Request a Pick Up checkbox.
For more information, take a look at our step-by-step guide.
How to: Schedule a USPS pickup for my packages
FAQs: USPS Pickup Requests
What is USPS Package Pickup?
Which address does USPS use when I request a pick-up?
Why didn't USPS pick up my packages when scheduled?